Journal of the Ceramic Association, Japan
Online ISSN : 1884-2127
Print ISSN : 0009-0255
ISSN-L : 0009-0255
Effect of Non-stoichiometry on the Sintering of TiNx
Keizo UEMATSUNobuo KIEDAOsamu SAKURAINobuyasu MIZUTANIMasanori KATO
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1982 Volume 90 Issue 1046 Pages 597-603

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Abstract
The effect of non-stoichiometry on the sintering of TiNx was studied at 1026°-1392°C for x=0.67-0.95. The rate of sintering decreased markedly with decreasing non-stoichiometry in TiNx. The results were tentatively analysed by the initial stage sintering equation. The diffusion coefficients of rate limiting species of sintering changed orders of magnitude for the region of non-stoichiometry studied. The relation between the defect concentration and the diffusion coefficient of rate limiting species of sintering was discussed. Sintering of TiNx was suggestedly controlled by the diffusion of nitrogen in the bulk.
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