Chemical and Pharmaceutical Bulletin
Online ISSN : 1347-5223
Print ISSN : 0009-2363
ISSN-L : 0009-2363
Studies on the Structure of Sciadopitysin, a Flavonoid from the Leaves of Sciadopitys verticillata SIEB. ET ZUCC. VII.
Nobusuke Kawano
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1959 Volume 7 Issue 6 Pages 698-701

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Abstract

1) 2, 2', 4, 6-Tetramethoxybiphenyl was obtained from substance B monomethyl ether, C19H20O7, by oxidation followed by decarboxylation, (II)→(III)→(IV)→(V), and it was also newly synthesized by the Ullmann reaction. 2) 4-Methoxyisophthalic acid was obtained from substance A (VIII) and B (VI) by oxidation. 3) The structure of sciadopitysin trimethyl ether was established as a new-type bisflavonoid of formula (VII) or (VII'), the former being preferable. 4) Formula (IX) or (X) was deduced as the structure of sciadopitysin.

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