Journal of Photopolymer Science and Technology
Online ISSN : 1349-6336
Print ISSN : 0914-9244
ISSN-L : 0914-9244
Directed Self-assembly of Topcoat-free, Integration-friendly High-χ Block Copolymers
Ankit VoraAnindarupa ChunderMelia TjioSrinivasan BalakrishmanElizabeth LofanoJoy ChengDaniel P. SandersEri HiraharaYasushi AkiyamaOrest PolishchukMargareta PaunescuDurairaj BaskaranSungEun HongGuanyang Lin
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2014 Volume 27 Issue 4 Pages 419-424

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Abstract

To extend the scaling beyond the most widely used poly(styrene-b-methyl methacrylate) (PS-b-PMMA), organic high-χ block copolymers (BCPs) were developed. Vertically oriented BCP domains were obtained by simple coat and bake process without application of an additional layer of a topcoat material. In addition, process-friendly conditions including low bake temperature (< 200 °C) and short bake time (≤ 5 min) provided a simple scheme to integrate these high-χ block copolymers to standard lithography process and pre-patterns defined by 193i lithography. Successful demonstration of directed self-assembly of these high-χ block copolymers on 193i-defined guiding pre-patterns offers a simple route to access well-aligned perpendicular lamellae and cylinders with a pitch less than 20 nm.

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© 2014 The Society of Photopolymer Science and Technology (SPST)
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