日本化学会誌(化学と工業化学)
Online ISSN : 2185-0925
Print ISSN : 0369-4577
3-(2-ヒドロキシエチル)-2-オキサゾリジノンの熱分解
石川 倶通山崎 康男
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1974 年 1974 巻 8 号 p. 1592-1594

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3-(2-Hydroxyethyl)-2-oxazolidinone (HEOX) was prepared by treating ethylenecarbonate with 2-oxazolidinone. A polymer was formed by heating HEOX at 240 C with sodium hydroxide under nitrogen until the evolution of carbon dioxide ceased completely. The amount of evolved earbon dioxide, the change ef infrared absorption spectra and the hydroxyl content of the product were measured. These results indicate that the polymer is best represented by the poly(2-hydroxyethy1)ethyleneimine structure containing the urea-bond and the etherbond in the polymer chain. This polymer was insoluble in common organic solvents.

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