粉体および粉末冶金
Online ISSN : 1880-9014
Print ISSN : 0532-8799
ISSN-L : 0532-8799
ゾルーゲル法による酸化物超伝導体の作製
作花 済夫幸塚 広光梅田 鉄門出 孝志金 基孫
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1988 年 35 巻 5 号 p. 339-343

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Superconducting YBa2Cu3O7-x fibers and coating films have been prepared using solgel method. Homogeneous viscous sol was prepared by concentrating an aqueous solution of metal acetates. Gel fibers of 5μm - 2 mm in diameter and of more than 50 cm in length could be drawn from the sol. Heat-treated fibers had a hollow structure and were fragile, but showed superconductivity of Tc(end) at 73 K. For preparation of YBa2Cu3O7-x coating films, metal alkoxide solution was prepared using triethanolamine to dissolve copper alkoxide. Repeated application of the solution on a zirconia substrate and heat treatment in O2 resulted in the formation of a superconducting coating film of 1.5 μm in thickness having Tc(end) at 56 K. Factors affecting the properties of the fibers and coating films have been discussed.

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