Elution Curve of Rutherfordium (Rf) in Anion-Exchange Chromatography with Hydrofluoric Acid Solution

A. Toyoshima; H. Haba; K. Tsukada; M. Asai; K. Akiyama; I. Nishinaka; Y. Nagame; D. Saika; K. Matsuo; W. Sato; A. Shinohara; H. Ishizu; M. Ito; J. Saito; S. Goto; H. Kudo; H. Kikunaga; N. Kinoshita; C. Kato; A. Yokoyama; K. Sueki

doi:10.14494/jnrs2000.5.45

A. Toyoshima, H. Haba, K. Tsukada, M. Asai, K. Akiyama, I. Nishinaka, Y. Nagame, D. Saika, K. Matsuo, W. Sato, A. Shinohara, H. Ishizu, M. Ito, J. Saito, S. Goto, H. Kudo, H. Kikunaga, N. Kinoshita, C. Kato, A. Yokoyama, K. Sueki

Author information

A. Toyoshima
Advanced Science Research Center , Japan Atomic Energy Research Institute
Graduate School of Science, Osaka University
H. Haba
Cyclotron Center
K. Tsukada
Advanced Science Research Center , Japan Atomic Energy Research Institute
M. Asai
Advanced Science Research Center , Japan Atomic Energy Research Institute
K. Akiyama
Advanced Science Research Center , Japan Atomic Energy Research Institute
I. Nishinaka
Advanced Science Research Center , Japan Atomic Energy Research Institute
Y. Nagame
Advanced Science Research Center , Japan Atomic Energy Research Institute
D. Saika
Graduate School of Science, Osaka University
K. Matsuo
Graduate School of Science, Osaka University
W. Sato
Graduate School of Science, Osaka University
A. Shinohara
Graduate School of Science, Osaka University
H. Ishizu
Faculty of Science, Niigata University
M. Ito
Faculty of Science, Niigata University
J. Saito
Faculty of Science, Niigata University
S. Goto
Faculty of Science, Niigata University
H. Kudo
Faculty of Science, Niigata University
H. Kikunaga
Graduate School of Science, Kanazawa University
N. Kinoshita
Graduate School of Science, Kanazawa University
C. Kato
Graduate School of Science, Kanazawa University
A. Yokoyama
Graduate School of Science, Kanazawa University
K. Sueki
Department of Chemistry, University of Tsukuba

JOURNAL FREE ACCESS

2004 Volume 5 Issue 2 Pages 45-48

DOI https://doi.org/10.14494/jnrs2000.5.45

Details

Abstract

An elution curve of element 104, rutherfordium (Rf), in anion-exchange chromatography has been obtained for the first time on an atom-at-a-time basis. The distribution coefficient in 5.4 M hydrofluoric acid solution has been determined to be 28±6 mL/g from the observed peak volume of the elution curve.

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