Simultaneous Observation of Volatility of Zr, Hf, and Rf Chlorides

Tetsuya Kaneko Sato; Kazuaki Tsukada; Masato Asai; Kazuhiko Akiyama; Hiromitsu Haba; Atsushi Toyoshima; Sawako Ono; Toshiyuki Hirai; Shin'ichi Goto; Shin'ichi Ichikawa; Yuichiro Nagame; Hisaaki Kudo

doi:10.14494/jnrs2000.6.2_N1

Tetsuya Kaneko Sato, Kazuaki Tsukada, Masato Asai, Kazuhiko Akiyama, Hiromitsu Haba, Atsushi Toyoshima, Sawako Ono, Toshiyuki Hirai, Shin'ichi Goto, Shin'ichi Ichikawa, Yuichiro Nagame, Hisaaki Kudo

Author information

Tetsuya Kaneko Sato
Department of Chemistry, Faculty of Science, Niigata University
Japan Atomic Energy Research Institute
Kazuaki Tsukada
Japan Atomic Energy Research Institute
Masato Asai
Japan Atomic Energy Research Institute
Kazuhiko Akiyama
Japan Atomic Energy Research Institute
Hiromitsu Haba
RIKEN, Wako
Atsushi Toyoshima
Japan Atomic Energy Research Institute
Graduate School of Science, Osaka University
Sawako Ono
Department of Chemistry, Faculty of Science, Niigata University
Toshiyuki Hirai
Department of Chemistry, Faculty of Science, Niigata University
Shin'ichi Goto
Department of Chemistry, Faculty of Science, Niigata University
Shin'ichi Ichikawa
Japan Atomic Energy Research Institute
Yuichiro Nagame
Japan Atomic Energy Research Institute
Hisaaki Kudo
Department of Chemistry, Faculty of Science, Niigata University

JOURNAL FREE ACCESS

2005 Volume 6 Issue 2 Pages N1-N3

DOI https://doi.org/10.14494/jnrs2000.6.2_N1

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Abstract

⁸⁵Zr, ¹⁶⁹Hf, and ²⁶¹Rf were produced simultaneously from ^natGe (¹⁸O, xn), ^natGd (¹⁸O, xn), and ²⁴⁸Cm (¹⁸O, 5n) reactions, respectively, and the volatility of their chlorides was examined using an isothermal gas chromatographic system. The observed gas chromatogram indicated that ZrCl₄, HfCl₄, and RfCl₄ had almost similar volatility.

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