高温学会誌
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研究論文
Flash Creation Methodを用いた青色蛍光体BaMgAl10O17:Eu2+の合成とその蛍光特性
渡辺 晃福井 武久野城 清戸田 健司川田 哲白倉 重樹細梅 雅史上松 和義佐藤 峰夫
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2008 年 34 巻 3 号 p. 130-135

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BaMgAl10O17:Eu2+ is a promising blue phosphor for lump, CRT and PDP. Conventionally, the BAM phosphors synthesize by the solid-state reaction from the mixture of oxide or carbonate starting materials. The solid-state reaction needs high temperature to get well-crystallized single phase. However, the control of particle morphology and size distribution is difficult for such a high temperature synthesis. In this study, we reported new synthetic technique using flash creation method derived nanopowder precursor. In the new technique, well-crystallized single phase phosphors were obtained at 1400°C for 6h. Although the powders were grown into the plate-like particles, the BAM powders retain the nano-size morphology after annealing. The emission intensity under UV excitation of Ba0.9Eu0.1MgAl10O17 from the FCM-derived nanopowder was 110% compared with phosphors prepared by the conventional solid-state reaction. The excitation intensity under VUV (146nm) of the FCM derived nanopowder was 159% of the conventional solid-state reaction.

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© 2008 (社)高温学会
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