Journal of the Ceramic Society of Japan
Online ISSN : 1882-1022
Print ISSN : 0914-5400
ISSN-L : 0914-5400
Structure, Oxygen Deficiency and Electrical Properties of Nd1-xYxNiO3-y (x=0, 0.1) Prepared by Sol-Gel Method
Shinobu FUJIHARAHiromitsu KOZUKAToshinobu YOKO
Author information
JOURNAL FREE ACCESS

1994 Volume 102 Issue 1191 Pages 1005-1009

Details
Abstract

Perovskite-type NdNiO3-y and Nd0.9Y0.1NiO3-y were prepared by heating the gel-derived powders at 700°C in flowing oxygen or in air for relatively short heating time of 20h, and the lattice constants, oxygen content, valence state of Ni ions and temperature dependence of the electrical resistance were measured. A new oxygen-deficient orthorhombic phase NdNiO3-y was found, which has larger lattice constants and lower metal-semiconductor (M-S) transition temperature than the previously known NdNiO3 phase. By substituting Y for Nd in the present NdNiO3-y, the lattice constants all decreased and the M-S transition temperature increased from 130 to 240K. The changes in the lattice constants and the M-S transition were discussed in terms of the ionic radius and the electronic bandwidth, respectively.

Content from these authors
© The Ceramic Society of Japan
Previous article Next article
feedback
Top